Cu 2p absorption spectroscopy as a probe for the site occupancy of (ZnxCu1−x)WO4 solid solution     

P. F. Schofield  C. M. B. Henderson  S. A. T. Redfern  G. van der Laan 《Physics and Chemistry of Minerals》1993,20(6):375-381

The solid solution sanmartinite (ZnWO₄)—cuproscheelite (CuWO₄) has been studied using Cu 2p X-ray absorption spectroscopy. While a single L₃ absorption peak is observed for CuWO₄, two distinct L₃ absorption peaks with a separation of ～0.8 eV are observed for the intermediate samples in the solid solution. The two peaks represent distinct Cu sites: one with all CuO₆ next nearest neighbours in the (Cu,Zn)O₆ chains, another having at least one ZnO₆ next nearest neighbour. Both sites show a linear increase in covalency as a function of increasing Cu-content. The relative intensities of the two absorption peaks is dependent upon the Cu-content and has been used to model the site occupancies. The results reveal that the local structural effects can be associated with a composition-dependent structural phase transition from P2/c (ZnWO₄) to P $\bar 1$ (CuWO₄). Deviations from a single-site model are explained in terms of the local environments, and evidence for site preferences and local clustering are explored.  相似文献   

A plan for a new generation 2M-class telescope in Indonesia     

Karel A. van der Hucht 《Astrophysics and Space Science》1984,99(1-2):409-410

One of the prime astrophysical interests of the Observatorium Bosscha is, and has always been, double star research: visual double star research with the double-60 cm Zeiss telescope (dedicated in 1928), and theoretical research of evolved massive spectroscopic binaries (since 1972). For one thing, this is the very reason that this IAU Colloquium No. 80, celebrating the 60th anniversary of the Observatorium Bosscha in Lembang, is devoted to binary astrophysics.Up to now, visual, photographic, and photometric tools have been used for binary research at the Observatorium Bosscha. An important, essential additional tool for binary research is spectrographic equipment, in order to measure radial velocities of binary components.Therefore, we suggest to make a plan for a new modern telescope, a reflector with a primary mirror of about 2 m in diameter and with a modern spectrograph/detector combination for radial velocity measurements.At a number of major astronomical observatories scientists have been considerating to erect new telescopes devoted primarily to radial velocity measurements. The reason for this is that at the end of this decade the parallax and proper motion measurements to be made by the ESA astrometric satellite Hipparcos will become available of more than 100 000 single stars and double stars. At that time there will be a compelling need for radial velocity measurements of all these stars to complement the parallax and proper motion measurements. With the combination of this data enormous progress will be made in double star research, and in the study of galactic dynamics, another topic of interest of the Observatorium Bosscha. If it could be realized to build such a dedicated radial velocity telescope in Indonesia, Indonesian astronomers could take a leading role in this field of research.Without going into technical details, we would like to emphasize here that such a new instrument should be a trueNew Generation Telescope, and that the Institut Teknologi Bandung should participate from the very beginning in its design, construction and assembling, and the subsequent servicing; ITB could participate in the field of optics, mechanics, and electronics. Modern astronomy offers tremendous challenges to technology, which are of great interest to technological institutes. The new telescope should be computer controlled, and the spectrograph should have a modern digital read-out (Reticon, IPCS, or CCD). The telescope should have one of those recently becoming availablethin mirrors, allowing more mechanical freedom. It could be a telescope with a siderostat which feeds the light into a fixed telescope, thus improving both the stability of the telescope and that of the spectrograph. In this way the staff and students of ITB, as well as the technical staff of the Observatorium Bosscha will be drawn into modern techniques of many varieties. And for ITB such an enterprise may even have a spin-off into other fields than astronomy.One aspect which is of great importance for the new telescope is the selection of its site. The present site of the Observatorium Bosscha in Lembang is a good one, but for a new modern telescope one wants to make sure that it is going to be located at the most ideal site.Therefore an Indonesian site-survey should be initiated promptly. Site survey equipment is available at many big observatories and could be borrowed. The site survey should extend over at least 4–5 years to monitor the meteorological and environmental situation at many sites.In the meantime the design and fund rainsing can be considered. Modern day astronomy depends on financial support from governments and inter-governmental organizations. Therefore it is urged that a proposal for a new telescope as indicated above clearly describes the advantages of such a new telescope both for astrophysical research in Indonesia, and for the introduction of new technologies in Indonesian technological institutes.The recently formed Steering Committee for Indonesian-Netherlands Astrophysics (INA) is willing to explore the possibilities for this plan. We hope that after investigating the interest of ITB in this matter, a proposal could be made before the end of this year.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia 3–7 June, 1983.  相似文献   

Developments in the characterisation of waste materials for environmental impact assessment purposes     

H.A. van der Sloot  J.C.L. Meeussen  A. van Zomeren  D.S. Kosson 《Journal of Geochemical Exploration》2006,88(1-3):72

The characterisation of waste is entering a new phase with the latest developments of characterisation leaching tests and associated modelling capabilities. The currently applied too simple testing approaches lead to poor choices in waste management. With the increased insight in release controlling processes chemical speciation aspects can be addressed even in the most complex and heterogeneous waste materials. From a composition perspective materials may be highly variable, but often materials are far more consistent in their leaching behaviour. This aspect should be exploited more extensively as it holds the key to treat waste materials in such a way that long term solutions are achieved rather than reaching temporary gains.  相似文献   

Precambrian fluvial deposits: Enigmatic palaeohydrological data from the c. 2–1.9 Ga Waterberg Group, South Africa     

Patrick G. Eriksson  Adam J. Bumby  Jacobus J. Brümer  Markus van der Neut 《Sedimentary Geology》2006,190(1-4):25-46

Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean–Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06–1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories.

Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450–489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to a combination of major global-scale tectono-thermal and atmospheric–palaeoclimatic events, a simpler explanation of these apparently enigmatic palaeoslope values may be pertinent. Of the two possible palaeohydrological formulae for calculating palaeoslope, one provides results close to typical fluvial gradients; the other formula relies on preserved channel-width data. We suggest that the latter will not be reliable due to problematic preservation of original channel-widths within an active braided fluvial system. We thus find no unequivocal support for a unique fluvial style for the Precambrian, beyond that generally accepted for that period and discussed briefly in the first paragraph.  相似文献   

Gender and voluntary work in late adulthood in rural communities in the Netherlands     

Joos Droogleever Fortuijn  Marieke van der Meer 《GeoJournal》2006,65(4):381-392

This article discusses the involvement of older women and men in voluntary work in rural communities in the Netherlands. Gender, ageing and civil society form the core concepts in the article. Politicians and policy makers in the Netherlands are worried about the perceived decline of civil society and about the consequences of this decline for specific categories of older women in terms of well-being and social exclusion. The paper presents the results of two surveys of involvement of older women and men in civic organisations, voluntary work and local actions. The surveys indicate high levels of involvement of both women and men. No gender differences are found in activity level. However, the data demonstrate the gendered nature of civil society. Women are more engaged in informal voluntary work and informal local actions, while men are more active in formal organisations and functions. This gender segmentation is not absolute, however. Many older women and men transgress the traditional feminine–masculine boundaries. The surveys highlight the involvement of women and men in rural communities, but indicate lower activity levels in urban areas.  相似文献   

Seismic buffer recognition using wavelet-based features and neural classification     

Alwyn Hoffman  Riaan Hoogenboezem  Theo van der Merwe  Tonie Tollig 《Geophysical Prospecting》2002,50(4):361-371

One of the first operations in a seismic signal processing system applied to earthquake data is to distinguish between valid and invalid records. Since valid signals are characterized by a combination of their time and frequency properties, wavelets are natural candidates for describing seismic features in a compact way. This paper develops a seismic buffer pattern recognition technique, comprising wavelet-based feature extraction, feature selection based on the mutual information criterion, and neural classification based on feedforward networks. The ability of the wavelet transform to capture discriminating information from seismic data in a small number of features is compared with alternative feature reduction techniques, including statistical moments. Three different variations of the wavelet transform are used to extract features: the discrete wavelet transform, the single wavelet transform and the continuous wavelet transform. The mutual information criterion is employed to select a relatively small set of wavelets from the time–frequency grid. Firstly, it is determined whether wavelets can capture more informative data in an equal number of features compared with other features derived from raw data. Secondly, wavelet-based features are compared with features selected based on prior knowledge of class differences. Thirdly, a technique is developed to optimize wavelet features as part of the neural network training process, by using the wavelet neural network architecture. The automated classification techniques developed in this paper are shown to perform similarly to human operators trained for this function. Wavelet-based techniques are found to be useful, both for preprocessing of the raw data and for extracting features from the data. It is demonstrated that the definition of wavelet features can be optimized using the classification wavelet network architecture.  相似文献   

Uniform postglacial slip-rate along the central 600 km of the Kunlun Fault (Tibet), from ²⁶Al, ¹⁰Be, and ¹⁴C dating of riser offsets, and climatic origin of the regional morphology     

Jerome Van Der Woerd  Paul Tapponnier  Frederick J. Ryerson  Anne-Sophie Meriaux  Bertrand Meyer  Yves Gaudemer  Robert C. Finkel  Marc W. Caffee  Zhao Guoguang  Xu Zhiqin 《Geophysical Journal International》2002,148(3):356-388

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Joint inversion of local, regional and teleseismic data for crustal thickness in the Eurasia–Africa plate boundary region     

Federica Marone  Mark van der Meijde  Suzan van der Lee  Domenico Giardini 《Geophysical Journal International》2003,154(2):499-514

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Receiver function study of the Hellenic subduction zone: imaging crustal thickness variations and the oceanic Moho of the descending African lithosphere   总被引：3，自引：0，他引：3  

X. Li  G. Bock  A. Vafidis  R. Kind  H.-P. Harjes  W. Hanka  K. Wylegalla  M. van der Meijde  X. Yuan 《Geophysical Journal International》2003,155(2):733-748

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阿尔金断裂带晚第四纪左旋走滑速率及其构造运动转换模式讨论   总被引：35，自引：2，他引：35  

徐锡伟  P.Tapponnier  J.Van Der Woerd  F.J.Ryerson  王峰  郑荣章  陈文彬  马文涛  于贵华  陈桂华  A.S.Meriaux 《中国科学D辑》2003,33(10):967-974

在高分辨率SPOT卫星数字影像和大比例尺航片处理、断错地貌制图、野外核实与位移测量基础上, 利用宇宙成因核素(¹⁰Be, ²⁶Al)、碳十四(¹⁴C)和热释光(TL)等多种测年手段, 厘定了各断错地貌面的形成年龄, 得到了阿尔金断裂带不同段落全新世左旋走滑速率: 阿克赛以西的中、西段左旋走滑速率可达(17.5±2) mm/a, 肃北-石包城段为(11±3.5) mm/a左右, 疏勒河口段减少到(4.8±1) mm/a左右, 东端宽滩山段仅约(2.2±0.2) mm/a, 左旋走滑速率突变点位于阿尔金断裂带中东段存在分支活动逆断层向南东扩展的肃北、石包城和疏勒河等三联点上. 矢量分析表明, 三联点东、西两侧左旋滑动速率的减少量转换成了阿尔金断裂带中东段南盘北西向活动逆断层上的地壳缩短和上盘推覆体抬升, 形成了党河南山、大雪山、祁连山等条块山地. 因此, 青藏高原北部物质向东挤出的速率和幅度是有限的, 符合“叠瓦状逆冲转换——有限挤出模型”.  相似文献